Gas-phase salt bridge interactions between glutamic acid and arginine

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Gas-phase salt bridge interactions between glutamic acid and arginine.

The gas-phase side chain-side chain (SC-SC) interaction and possible proton transfer between glutamic acid (Glu) and arginine (Arg) residues are studied under low-temperature conditions in an overall neutral peptide. Conformation-specific IR spectra, obtained with the free electron laser FELIX, in combination with density functional theory (DFT) calculations, provide insight into the occurrence...

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ژورنال

عنوان ژورنال: Physical Chemistry Chemical Physics

سال: 2013

ISSN: 1463-9076,1463-9084

DOI: 10.1039/c3cp52508b